Can anyone 'splain this?
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I don't know that it's the rig that causes this but I have no idea what does. It looks somewhat like gymbal lock (not that I have much experience with that) but the IK hand null is set to Quaternion so that shouldn't be it.
the chor is 2_02_22_v03weirdhandturn.cho if you want to try it at 06:05
other bones I'm posing on this characer haven't done this yet. I do seem to have the current version of Tinwoodman.